Coupling Reactions Initiated by Oxidative Addition to Au(I) Complexes
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چکیده
منابع مشابه
Cooperative bimetallic oxidative addition reactions*
The factors that control the oxidation of metals in bimetallic complexes are investigated in relation to the possibility of developing one-site addition two-metal oxidation reactions such as those that occur in the respiratory protein, hemerythrin. It is shown that the behavior of bimetallic complexes is not represented by the sum of the analogous monometallic parts because of metal and ligand ...
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Many nickel-based catalysts have been reported for cross-coupling reactions of nonactivated alkyl halides. The mechanistic understanding of these reactions is still primitive. Here we report a mechanistic study of alkyl-alkyl Kumada coupling catalyzed by a preformed nickel(II) pincer complex ([(N2N)Ni-Cl]). The coupling proceeds through a radical process, involving two nickel centers for the ox...
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[*] Prof. J. L. Beauchamp, R. R. Julian Beckman Institute California Institute of Technology Pasadena, CA 91125 (USA) Fax: (+1)626-568-8641 E-mail: [email protected] Prof. B. M. Stoltz, J. A. May The Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering California Institute of Technology Pasadena, CA 91125 (USA) Fax: (+1)626-564-9297 ...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 2021
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.79.155